Home Knowledge Base Ruthenium Interconnect

Ruthenium (Ru) is an emerging interconnect metal for advanced nodes where its properties outperform copper at the smallest dimensions, addressing the resistivity scaling crisis in BEOL. Why Ru: at line widths below ~15nm, Cu resistivity increases dramatically due to electron scattering at grain boundaries and surfaces (mean free path of Cu ≈ 39nm). Ru has shorter mean free path (~6nm), so resistivity increases less at small dimensions. Key advantages: (1) Lower effective resistivity at sub-15nm widths—Ru becomes competitive with or better than Cu; (2) No barrier needed—Ru is a self-barrier (doesn't diffuse into dielectric like Cu), saving barrier volume that otherwise reduces Cu volume; (3) No seed layer—Ru can be deposited directly by CVD/ALD; (4) Better electromigration—higher melting point and stronger bonding. Integration approach: (1) Subtractive etch—deposit Ru blanket film, pattern with hard mask, etch (vs. Cu damascene); (2) Damascene—fill trenches with Ru using CVD, CMP; (3) Hybrid—Ru for narrow lines (local interconnect), Cu for wider lines (semi-global/global). Deposition: CVD or ALD using Ru precursors (carbonyls, amidinates), achieving conformal fill. Etch: Ru etching uses O₂-based plasma chemistry (forms volatile RuO₄). Challenges: (1) Ru deposition cost—expensive precursors; (2) CMP—Ru harder to polish than Cu; (3) Etch—requires new etch chemistry development; (4) Integration—interface engineering with adjacent materials. Industry status: under active development at Intel, TSMC, Samsung for 2nm and beyond—Ru likely for M1/M2 (tightest pitch), Cu retained for upper metals. Part of broader BEOL material transition including molybdenum and alternative barrier approaches.

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