liner deposition cmos
**Liner Deposition** is the **thin film deposited on via and trench sidewalls and bottoms before filling with metal** — providing adhesion, diffusion barrier, and nucleation functions that ensure reliable metal interconnect formation.
**Why Liners Are Needed**
- Copper diffuses rapidly through SiO2 and Si → kills transistors.
- Tungsten doesn't adhere to SiO2 directly → delamination.
- Liners provide: diffusion barrier (Cu), adhesion (W), nucleation surface for CVD/ELD.
**Contact Liner (W Contacts)**
**Ti Adhesion Layer**:
- PVD Ti, 5–20nm.
- Reacts with Si at contact bottom: Ti + Si → TiSi2 (lowers contact resistance).
- Provides adhesion for TiN above.
**TiN Barrier Layer**:
- CVD or PVD TiN, 10–30nm.
- Diffusion barrier: Prevents W from reacting with Si.
- Nucleation layer: CVD W nucleates uniformly on TiN (poor on SiO2).
**Copper Via/Trench Liner (Dual Damascene)**
**TaN Diffusion Barrier**:
- ALD or iPVD TaN, 2–4nm at advanced nodes.
- Excellent Cu diffusion barrier: Activation energy > 1.5 eV.
- Must be conformal in high-AR features (AR > 10:1).
**Cu Seed Layer**:
- PVD Cu, 10–50nm — nucleation layer for Cu electroplating.
- Must be continuous even at bottom corners — gap-fill challenge.
- At 5nm node: Seed may be replaced by fully-CVD or ALD Cu.
**Scaling Challenge**
- At 5nm node: TaN + Cu seed = 5–8nm of overhead in a 10nm-wide trench.
- Alternative barriers: Co, Ru metal barriers (< 2nm effective) — enable thinner liners.
- Ruthenium liner: Direct-plate without Cu seed, better resistivity, thinner possible.
Liner deposition is **a critical integration challenge at each technology node** — balancing barrier effectiveness with the overhead cost of film thickness becomes increasingly difficult as feature sizes approach single-digit nanometers.