RF Magnetron Sputtering
RF, pulsed-DC, and reactive sputtering extend standard DC magnetron sputtering to handle targets and films that plain DC power can't deposit well — insulating target materials, arc-prone compound films, and reactively formed compound coatings respectively. Each modifies how power is delivered to the sputtering target to solve one specific problem DC sputtering runs into.
RF sputtering exists because a pure DC discharge simply can't sustain itself on an insulating target at all. DC sputtering relies on a continuous current flowing through the target to the plasma; an insulating or dielectric target would just accumulate positive charge from ion bombardment until the discharge extinguished itself, since there's no conduction path for that charge to drain away. An alternating RF field solves this by reversing polarity fast enough that the target's surface charge never has time to build up and choke the discharge, which is why RF sputtering — not DC — is the standard approach whenever the target material itself is a dielectric.
Pulsed-DC sputtering and reactive sputtering are frequently combined precisely because reactive sputtering's own byproduct creates the arcing problem pulsed-DC exists to solve. When a metal target sputters in the presence of reactive gas, a thin insulating compound layer can form directly on the target's own surface — the same arc-causing charge-buildup problem RF solves for a bulk insulator, but now happening locally on an otherwise-conductive metal target. Pulsing the DC power clears that localized charge before it triggers a damaging arc, which is why reactive sputtering processes depositing oxides or nitrides so often run on pulsed-DC power rather than plain continuous DC.
RF, pulsed-DC, and reactive sputtering aren't separate deposition technologies so much as three targeted fixes layered onto the same basic magnetron sputtering mechanism, each addressing a specific way that a simple continuous DC discharge breaks down for a particular target material or target film chemistry.