nanosheet stack

**Nanosheet SiGe/Si Superlattice** is the **epitaxially grown alternating stack of thin SiGe and Si layers that forms the starting material for gate-all-around (GAA) nanosheet transistors** — where selective removal of the SiGe sacrificial layers releases the Si nanosheets that become the transistor channels, with stack quality directly determining device performance and yield. **Superlattice Structure** - Typical stack: 3-5 pairs of alternating SiGe/Si layers on Si substrate. - Each layer: 5-12 nm thick — precisely controlled by epitaxial growth. - Example (3nm node): SiGe(8nm)/Si(6nm)/SiGe(8nm)/Si(6nm)/SiGe(8nm)/Si(6nm)/SiGe(8nm). - Bottom SiGe layer acts as isolation from substrate. **Epitaxial Growth Requirements** | Parameter | Specification | Impact | |-----------|--------------|--------| | Si thickness uniformity | ± 0.3 nm across wafer | Vt variation | | SiGe thickness uniformity | ± 0.5 nm across wafer | Release etch selectivity | | Ge composition (25-30%) | ± 1% across wafer | Etch selectivity to Si | | Interface sharpness | < 1 nm transition | Carrier scattering | | Defect density | < 0.1/cm² | Yield | **Growth Process** - **RPCVD (Reduced Pressure Chemical Vapor Deposition)**: Standard tool for superlattice growth. - Temperature: 500-700°C. - Precursors: SiH2Cl2 (DCS) for Si, GeH4 + SiH2Cl2 for SiGe. - Pressure: 10-50 Torr. - **Growth Rate**: ~1-5 nm/min — slow for thickness control. - **In-Situ Doping**: B2H6 or PH3 added for n-well/p-well doping during growth. **Channel Release Process** 1. **Fin patterning**: Superlattice stack etched into fin shape. 2. **Dummy gate formation**: Covers channel region. 3. **Source/drain etch and epi**: Lateral SiGe layers exposed. 4. **Inner spacer formation**: Etch lateral SiGe recess near gate, fill with dielectric. 5. **SiGe sacrificial removal**: Selective vapor-phase or wet etch removes all SiGe layers. - Chemistry: Peracetic acid or vapor HCl — etches SiGe > 100:1 selectivity to Si. 6. **Gate wrap-around**: High-k/metal gate deposited around released Si nanosheets. **Stacking Variants** - **3 nanosheets**: Current production (Samsung 3nm, Intel 20A). - **4 nanosheets**: Planned for next generation — more drive current per footprint. - **CFET (Complementary FET)**: NMOS nanosheet stack on top of PMOS stack — ultimate density. The SiGe/Si superlattice is **the foundation of the GAA nanosheet transistor era** — epitaxial growth quality at the angstrom level directly controls the threshold voltage uniformity, drive current, and yield of every nanosheet transistor fabricated at 3nm and beyond.

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